Marking the subject with が
Identify who does something, or what exists.

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が marks the subject: who acts or what exists. 猫 が います means “There is a cat,” and けんさん が 来ます means “Ken is coming.” The noun before が tells you who or what the statement is about grammatically.
English often signals the subject through its position before the verb. Japanese uses particles to make roles clear, and its verbs do not change for “I,” “you,” or “they.” が helps identify the subject when it needs to be stated.
Use が with “who?” when asking someone’s identity or role: 「誰 が 先生 です か。」→「けんさん が 先生 です。」 Here the answer identifies Ken as the teacher. That identifying emphasis comes from the question and context; が does not always mean “and nobody else.”
Examples
誰 が けんさん です か。
Who is Ken?
けんさん が 先生 です。
Ken is the teacher.
lit. Ken [identified as the subject] is the teacher.
猫 が います。
There is a cat.
木 が 大きい です。
The tree is big.